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Raman study of ion-molecules interaction in poly(Methylmetacrylate)-Based gel electrolytes

TitleRaman study of ion-molecules interaction in poly(Methylmetacrylate)-Based gel electrolytes
Publication TypeArticolo su Rivista peer-reviewed
Year of Publication1996
AuthorsCazzanelli, E., Mariotto G., Appetecchi Giovanni Battista, and Croce F.
JournalIonics
Volume2
Pagination81-87
ISSN09477047
Abstract

Gel electrolytes have been obtained, containing LiX (X = CIO4, N(CF3SO)2, AsF6) dissolved in a ethylene carbonate-propylene carbonate mixture and PMMA as polymeric matrix. Ionic conductivity has been measured, for two different lithium salts. The changes in the Raman spectra have been studied as a function of the polymer content, lithium salt concentrations and for different anions. Two satellite bands of the internal bending and stretching modes of ethylene carbonate appear in the spectrum of lithium containing samples, because of the cation-solvent molecule interaction.

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URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0002048737&partnerID=40&md5=cfec74ab7cc4eb699b9d90739ce0f5bf
Citation KeyCazzanelli199681