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Investigation on the stability of the lithium-polymer electrolyte interface

TitoloInvestigation on the stability of the lithium-polymer electrolyte interface
Tipo di pubblicazioneArticolo su Rivista peer-reviewed
Anno di Pubblicazione2000
AutoriAppetecchi, Giovanni Battista, Scaccia S., and Passerini S.
RivistaJournal of the Electrochemical Society
Volume147
Paginazione4448-4452
ISSN00134651
Parole chiaveEnvironmental impact, Filler metals, Interfaces (materials), Lithium compounds, Lithium-polymer electrolyte interface, Polyelectrolytes, Thermodynamic stability
Abstract

In this paper is reported an investigation on the stability of the interface formed by polyethene oxide (PEO)-based polymer electrolytes in contact with lithium metal anodes. In particular, the investigation was oriented to determine the effect of the composite electrolyte preparation procedure and environment and the filler addition as well as the cell assembly procedure on the interfacial properties of PEO-LiCF3SO3/Li half cells. The stability investigation was performed at the operative temperature (90 °C) of the electrolyte (PEO20LiCF3SO3) in rest condition as well as during continuous lithium plating/stripping cycles. The results indicate that the preparation procedure and the environment play major roles with respect to the addition of the filler.

Note

cited By 89

URLhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0034513117&doi=10.1149%2f1.1394084&partnerID=40&md5=83c8bed2becf62a61dc3167b33cd2a21
DOI10.1149/1.1394084
Citation KeyAppetecchi20004448